{"id":4157,"date":"2019-07-28T15:56:32","date_gmt":"2019-07-28T22:56:32","guid":{"rendered":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/?p=4157"},"modified":"2019-07-28T16:04:49","modified_gmt":"2019-07-28T23:04:49","slug":"naming-iupac-nomenclature-2","status":"publish","type":"post","link":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/organicchemistry\/naming-iupac-nomenclature-2\/","title":{"rendered":"Naming\/ IUPAC Nomenclature 2"},"content":{"rendered":"\n<p>Now that you have the basics of naming, here are some tips on prioritization rules (i.e. giving functional groups priority or the lowest position number).<\/p>\n\n\n\n<ul class=\"wp-block-list\"><li><strong>Double bond &#8220;-enes&#8221;<\/strong> have priority over triple bond &#8220;-ynes&#8221;.<\/li><li><strong>Triple bond<\/strong> -ynes get priority over over phenyl.<\/li><li><strong>Halides\/halogens<\/strong> have no special priority over alkyl groups.<\/li><li>In general, you can expect any functional group containing an oxygen will have priority over functional groups without the oxygen.<\/li><li><strong>Alcohol <\/strong>has priority over alkyl, amines, halides, ethers, phenyl, and thiols.<\/li><li><strong>Thiols <\/strong>-SH get priority over alkyl and halides. <\/li><li>If both thiols and alcohols are present, then alcohol gets priority.<\/li><li><strong>Aldehyde <\/strong>gets priority over double bond -enes and alcohol.<\/li><li><strong>Carboxyl <\/strong>group gets priority over aldehydes.<\/li><li><strong>Ketones <\/strong>get priority over -enes, phenyls, and alcohols.<\/li><li><strong>Carboxylic acids<\/strong> are highest priority and are terminal; there can only be a maximum of two carboxylic acids. Carboxylic acids get priority over alcohols, amines, ketones and aldehydes.<\/li><li>Non carboxylic acid <strong>carbonyls <\/strong>(acting as substituents) get the &#8220;oxo&#8221; name.<\/li><li><strong>Esters <\/strong>have priority over carboxylic acids and the nitrile group.<\/li><li>Groups with oxygen have priority over amines.<\/li><li><strong>Amides <\/strong>get priority over amines.<\/li><\/ul>\n","protected":false},"excerpt":{"rendered":"<p>Now that you have the basics of naming, here are some tips on prioritization rules (i.e. giving functional groups priority or the lowest position number). Double bond &#8220;-enes&#8221; have priority over triple bond &#8220;-ynes&#8221;. Triple bond -ynes get priority over over phenyl. Halides\/halogens have no special priority over alkyl groups. In general, you can expect [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[20],"tags":[],"class_list":["post-4157","post","type-post","status-publish","format-standard","hentry","category-organicchemistry"],"_links":{"self":[{"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/posts\/4157","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/comments?post=4157"}],"version-history":[{"count":4,"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/posts\/4157\/revisions"}],"predecessor-version":[{"id":4161,"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/posts\/4157\/revisions\/4161"}],"wp:attachment":[{"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/media?parent=4157"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/categories?post=4157"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/integrativewellnessandmovement.com\/iwmbasicscience\/wp-json\/wp\/v2\/tags?post=4157"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}