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Alkenes

  • Alkenes have at least one double bond in their structure.
  • The general formula is C(n)H(2n).
  • They are unsaturated.
  • When naming, specify the positional number of the beginning of the double bond. Try to assign the lowest numbers to the double bond. Alkenes get priority over alkynes.
  • If there is more than one double bond, use di-, tri-, etc.
  • Alkenes end in -ene suffix.
  • Naming: double and then triple bonds get priority over alkyl and halogen groups.
  • Alkenes and cycloalkanes can have cis- (same side) and trans- (opposite sides) descriptors. Cis- and trans- are specified at the beginning of the name.
  • Alkenes may be cyclic.
  • Nonpolar. London forces are additive. When comparing, size comes first then packing efficiency.
  • The benzene ring (aromatic) is a special case of a cyclical alkene where the cyclohexene alternates between double and single bonds all the way around the ring. This special structure has resonance and the aromatics have a category all of their own.